Melting Point Depression and Phase Transformation of KNO<sub>3</sub> Crystal Impregnated into Porous Glass
نویسندگان
چکیده
منابع مشابه
Crystal-amorphous and crystal-crystal phase transformations via virtual melting.
A new mechanism of crystal (c)-amorphous (a) and c-c phase transformations (PTs) and internal stress relaxation via virtual melting (VM) induced by internal stresses was justified thermodynamically and kinetically. VM removes interface friction, reduces kinetic barrier, increases atomic mobility, and can reduce thermodynamic melting temperature. We combine VM and nonequilibrium PT diagrams to d...
متن کاملcompactifications and representations of transformation semigroups
this thesis deals essentially (but not from all aspects) with the extension of the notion of semigroup compactification and the construction of a general theory of semitopological nonaffine (affine) transformation semigroup compactifications. it determines those compactification which are universal with respect to some algebric or topological properties. as an application of the theory, it is i...
15 صفحه اولSolid-solid phase transformation via internal stress-induced virtual melting, significantly below the melting temperature. Application to HMX energetic crystal.
We theoretically predict a new phenomenon, namely, that a solid-solid phase transformation (PT) with a large transformation strain can occur via internal stress-induced virtual melting along the interface at temperatures significantly (more than 100 K) below the melting temperature. We show that the energy of elastic stresses, induced by transformation strain, increases the driving force for me...
متن کاملA kinetic model of the transformation of a micropatterned amorphous precursor into a porous single crystal.
Biogenic single crystals with complex shapes are believed to be generated by the crystallization of an amorphous precursor. Recent biomimetic experiments on the crystallization of calcite via amorphous-to-crystalline transition point to the fact that the transformation kinetics may be controlled by the micropattern and the macroscopic shape of the amorphous precursor phase. Here we analyse a si...
متن کاملSize-dependent melting point depression of nanostructures: Nanocalorimetric measurements
The melting behavior of 0.1–10-nm-thick discontinuous indium films formed by evaporation on amorphous silicon nitride is investigated by an ultrasensitive thin-film scanning calorimetry technique. The films consist of ensembles of nanostructures for which the size dependence of the melting temperature and latent heat of fusion are determined. The relationship between the nanostructure radius an...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the Ceramic Association, Japan
سال: 1984
ISSN: 0009-0255,1884-2127
DOI: 10.2109/jcersj1950.92.1066_341